Product ID:COMPOUND ZC-16 REPLENISHER
MSDS Date:04/30/1990
FSC:6850
NIIN:00N011575
MSDS Number: BJFHX

MADISON CHEMICAL CO,INC

STATE ROAD 62
MADISON, IN 47250
US

Emergency Phone: 812-273-6000 WK DAYS;812 (SUP DATA)

Info Phone: 812-273-6000

Preparer: STEVEN T HALE

Cage: 60142

MADISON CHEMICAL CO INC

125 MADISON, IN 47250 US

Cage: 60142

PHOSPHORIC ACID (SARA III)

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: 14% MAX

OSHA PEL 1 MG/M3/3 STEL

ACGIH TLV: 1 MG/M3/3 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PROLONGED OR REPEATED OVEREXPOSURE
WITHOUT FIRST AID TREATMENT MAY CAUSE BURNS.MAY BE HARMFUL IF
SWALLOWED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IRRITATION.SKIN:CONTACTED AREAS WILL
EXHIBIT IRRITATION.INGESTION:MAY BE HARMFUL IF
SWALLOWED.INHALATION:CAUSES IRRITATION TO MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:IMMEDIATELY FLUSH WITH LARGE QUANTITIES OF COOL WATER
CONTINUOUSLY FOR AT LEAST 15 MIN.CALL MD.SKIN:IMMED FLUSH W/ LARGE
QUANTITIES OF COOL WATER CONTINUOUSLY FOR AT LEAST 15 MIN.CALL
MD.REMOVE C ONTAM CLOTHING & SHOES.INGESTION:DO NOTINDUCE
VOMITING.GIVE WATER.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.CALL MD.INHAL:REMOVE TO FRESH AIR.IF SYMPTOMS ARE
PRESENT,GET MED ATTENTION.

Flash Point Method:TOC
Flash Point:NONE TO BOILING
Extinguishing Media:AS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION
PRODUCTS:PHOSPHORUS OXIDES,NITROGEN OXIDES.

Spill Release Procedures:CONTAIN LIQUID SPILLS W/ SAND AND ABSORB ON
SODA ASH.DISPOSE WITH SOLID WASTES.SEE WASTE DISPOSAL METHOD.
Neutralizing Agent:N/K

Handling and Storage Precautions:NORMAL FOR ACIDS.
Other Precautions:FOR INDUSTRIAL USE ONLY.KEEP OUT OF THE REACH OF
CHILDREN.MAY BE HARMFUL IF SWALLOWED.CONTAINS PHOSPHORIC ACID.

Respiratory Protection:USE NIOSH/MSHA APPROVED INORGANIC ACID VAPOR
RESPIRATOR FOR AREAS WHERE AIRBORNE IS EXCESSIVE.
Ventilation:USE GOOD VENTILATION.LOCAL EXHAUST IS RECOMMENDED IF TLV'S
ARE EXCEEDED.
Protective Gloves:IMPERMEABLE TYPE
Eye Protection:GOGGLES AND FACESHIELD NECESSARY.
Other Protective Equipment:RUBBER APRON & BOOTS REQUIRED & OTHER EQUIP
AS NEC TO AVOID CONTACT.EYEWASH FACILITY & EMER SHOWER IN CLOSE
PROXIMITY.
Work Hygienic Practices:WASH CLOTHING & SHOES THOROUGHLY IN SOAP &
WATER;RINSE REPEATEDLY IN CLEAN WATER & DRY BEFORE REUSE.
Supplemental Safety and Health
MFR EMER TEL NO:265-2703,812-273-6213 EVENINGS,WEEKENDS.ROUTES OF
ENTRY:EYES (MFR);INGESTION .PH:2.0-2.3 (1% BY VOLUME);0.3-0.5
(100%).

Boiling Pt:B.P. Text:230F,110C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Spec Gravity:1.48 (WATER=1)
pH:SUP DA
Evaporation Rate & Reference:1.0 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,WATER-WHITE LIQUID WITH A MILD ODOR.

Stability Indicator/Materials to Avoid:YES
ALKALINE MATERIALS,REDUCING AGENTS.
Hazardous Decomposition Products:PHOSPHORUS OXIDES,NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .NORMAL FOR ACIDIC WASTES
CONTAINING PHOSPHATES AND ZINC COMPOUNDS.MAY REQUIRE PH ADJUSTMENT
FOR NEUTRALIZATION.PHOSPHORIC ACID:SARA TITLE III SECTION 313
LISTED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.